Bis(dihydrogen norfloxacinium) tri-μ2-chlorido-bis[trichloridobismuthate(III)] chloride dihydrate
نویسندگان
چکیده
The title compound, {systematic name: (3-carb-oxy-1-ethyl-6-fluoro-7-piperazin-4-ium-1-yl-1H-quinolin-4-yl-idene)oxonium tri-μ(2)-chlorido-bis-[trichloridobismuthate(III)] chloride dihydrate], (C(16)H(20)FN(3)O(3))(2)[Bi(2)Cl(9)]Cl·2H(2)O, is composed of [Bi(2)Cl(9)](3-) anions lying on crystallographic twofold rotation axes, Cl(-) anions also on twofold axes, C(16)H(20)FN(3)O(3) (2+) cations, and water mol-ecules. The Bi(III) coordination polyhedron is a distorted octa-hedron and two such octa-hedra share a triangular face to form the complex anion. There are three short terminal Bi-Cl bonds [2.5471 (6)-2.5781(5 Å] and three longer bridging bonds [2.8599 (5)-2.9984 (6) Å] in each octa-hedron. Anions, cations and water mol-ecules are linked by hydrogen bonds to form a three-dimensional network. There are also π-π stacking inter-actions between quinoline ring systems, with an inter-planar distance of 3.27 (1) Å.
منابع مشابه
Tetrakis(dihydrogen pefloxacinium) di-μ2-chlorido-bis[tetrachloridobismuthate(III)] tetrachloride octahydrate
The title compound {systematic name: tetra-kis[4-(3-carb-oxy-1-ethyl-6-fluoro-4-hydroxonio-1,4-dihydro-7-quinol-yl)-1-meth-yl-piperazin-1-ium] di-μ(2)-chlorido-bis-[tetra-chlorido-bismuth-ate(III)] tetra-chloride octa-hydrate}, (C(17)H(22)FN(3)O(3))(4)[Bi(2)Cl(10)]Cl(4)·8H(2)O, is composed of edge-shared centrosymmetric dinuclear [Bi(2)Cl(10)](4-) anions, Cl(-) anions, dihydrogen pefloxacinium ...
متن کاملCrystal structure of the new hybrid material bis(1,4-diazoniabicyclo[2.2.2]octane) di-μ-chlorido-bis[tetrachloridobismuthate(III)] dihydrate
The title compound bis-(1,4-diazo-niabi-cyclo-[2.2.2]octa-ne) di-μ-chlorido-bis-[tetra-chlorido-bis-muthate(III)] dihydrate, (C6H14N2)2[Bi2Cl10]·2H2O, was ob-tain-ed by slow evaporation at room temperature of a hydro-chloric aqueous solution (pH = 1) containing bis-muth(III) nitrate and 1,4-di-aza-bicyclo-[2.2.2]octane (DABCO) in a 1:2 molar ratio. The structure displays a two-dimensional arran...
متن کامل[N,N′-Bis(2,6-diisopropylphenyl)pentane-2,4-diamine(1–)-2κ2 N,N′]-μ2-chlorido-1:2κ2 Cl:Cl-chlorido-2κCl-bis(1,2-dimethoxyethane-1κ2 O,O′)iron(II)lithium
In the title compound, [FeLi(C(29)H(41)N(2))Cl(2)(C(4)H(10)O(2))(2)], the Fe(II) atom is coordinated by two N and two Cl atoms, generating a distorted FeN(2)Cl(2) tetra-hedral geometry. Additionally, one of the chloride atoms bridges to a lithium ion, which is solvated by two dimethoxy-ethane mol-ecules and is coordinated in a distorted trigonal-bipyramidal environment. The central Fe, Cl (× 2)...
متن کاملTrimethylphosphonium trans-tetrachloridobis(trimethylphosphane-κP)iridate(III)
The title compound, [HP(CH3)3][IrCl4{(H3C)3P}2], consists of a tri-methyl-phospho-nium cation and a tetra-chlorido-bis-(tri-methyl-phosphane)iridate(III) anion. The anion has an octa-hedral arrangement of ligands, with the tri-methyl-phosphane groups occupying trans positions. The Ir(III) atom sits on an inversion center with one P(CH3)3 ligand and two chloride ligands in the asymmetric unit. T...
متن کاملDi-μ-chlorido-bis{bis[3,5-dimethylpyrazol-1-yl-κN 2)methane]iron(II)} bis[tetrachloridoferrate(III)]
In the title complex, [Fe(2)Cl(2)(C(11)H(16)N(4))(4)][FeCl(4)](2), the asymmetric unit is composed of one and a half units of [Fe(bdmpm)(2)Cl](2)(FeCl(4))(2)(bdmpm = bis(bis(3,5-dimethyl-pyrazol-1-yl)methane). The three independent Fe(II) atom have a distorted octa-hedral coordination geometry comprising two bridging chloride anions and four N atoms from two bis-(3,5-dimethyl-pyrazol-1-yl)metha...
متن کامل